对二(4'-N,N-二苯氨基苯乙烯基)苯和对二(4'-硝基苯乙烯基)苯的合成及其荧光光谱

合成了两种具有大π共轭性的二苯乙烯类衍生物,通过1H NMR对它们进行了鉴定.单光子荧光光谱及双光子上转换荧光的测定发现它们存在一定的上转换荧光.     

Structure of BaGd2（MoO4）4 Crystal

The title compound belongs to monoclinic,space group C2/c with a=5.2694(1),b=12.6659(4),c=19.4108(2) ,β=91.504(2)°,V=1295.06(5) 3,Z=4 and Dc=5.599 g/cm3. The structure of BaGd2(MoO4)4 contains a MoO4 tetrahedron,a distorted GdO8 polyhedron,and Ba2+ ions in a tenfold coordination. The GdO8 polyhedra are linked together through edge-sharing to give a two-dimensional Gd layer. The MoO4 tetrahedra connected to the Gd atoms are capped up and down the Gd layer through common oxygen apices,thus forming a new Gd-Mo layer. Finally,the Gd-Mo layers are held together through bridging BaO10 polyhedra to form a three-dimensional framework. Since the Ba-μ3-O bond has a large average distance of 2.888 ,this structural characteristic will result in a cleavage along the (001) plane.     

两角和与差的三角函数

1．本单元重、难点分析 本单元的重点是：两角和与差的正弦、余弦、正切公式；二倍角的正弦、余弦、正切公式；运用公式进行简单三角函数式的化简、求值与恒等式证明．     

两角和与差的三角函数

1.本单元重、难点分析本单元的重点是:两角和与差的正弦、余弦、正切公式;二倍角的正弦、余弦、正切公式;运用公式进行简单三角函数式的化简、求值与恒等式证明.本单元的难点有:余弦的和角公式的推导;各公式之间的异同及其内在联系;和角公式、差角公式、倍角公式与以前学过的同角三角函数的基本关系式、诱导公式的综合运用.通过公式的推导,了解各公式之间的内在联系,可以培养学生的逻辑推理能力;通过本节的学习,学生进一步了解符号与变元、集合与对应、数形结合、化归等基本数学思想在研究三角函数时所起的重要作用;在三角函数式的变化中,学…     

Synthesis and Crystal Structural Characterization of a Thiosemicarbazone Derived from 4-Acylpyrazolone

1 INTRODUCTION Pyrazol-5-one derivatives form an important class of organic compounds due to their structural che- mistry and biological activities as analgesic, antipy- retic, anti-inflammatory and hyperglycemic agents[1～4]. Even the simplest pyrazol-5-one derivatives like antipyrine and amidopyrine are widely used in anal- gesic medicine[5, 6]. On the other hand, thiosemicar- bazones, especially heterocyclic thiosemicarbazones, have been the subject of extensive investigations be- cause…     

Synthesis and Crystal Structure of N, N'''''''',N''''''''-Tris-(2-oxynaphthalidene)-tris-(2-iminoethyl) Amine

1 INTRODUCTION Schiff’s bases are well known ligands representedby many bi-, tri-, tetra-, and hexa-dentate example-es[1], but heptadentate ligands are relatively rare[2, . 3]We have reported a copper complex of tetradentateSchiff’s bases[4]…     

Synthesis and Crystal Structure of Ethyl 2,7,7-Trimethyl-4-(4''''-methylphenyl)- 5-oxo-1,4,5,6,7,8-hexahydroquinoline-3- carboxylate in Aqueous Medium

1 INTRODUCTION The 1,4-dihydropyridines (1,4-DHPs) are biologi- cally interesting compounds and have been developed extensively in pharmacology. 1,4-DHP derivatives are used therapeutically in the treatment of cardio- vascular disorders, especially hypertension and coro- nary heart disease such as angina pectoris, atheros- clerosis, etc. The DHPs have emerged as one of the most important classes of drugs for the treatment of gastrointestinal disease, Raynaud?s disease, pulmonary hyper…     

非饱和土壤水一维水平运动方程的拟解析解及其验证

本文讨论了土壤一维不饱和水平流方程的解析解问题，文中首先根据土壤水扩散率Ｄ与土壤含水量θ之间的经验关系，对原土壤水一维不饱和流方程作变量代换，将方程变为易于求解的形式，然后采用变量分离的方法并结合Ｂｏｌｔｚｍａｎｎ变换法进行求解，从而得出了解析表达式。     

认股权证的等价鞅测度定价模型与数值方法

本文对认股权证应用等价鞅测度方法进行定价 .推导出计算更自然、更简单的类似 Black- Scholes模型的认股权证定价公式 .给出了一种比较好的数值计算方法 .并讨论了认股权证在中国证券市场的发展状况 .     

马钱子中两种微量生物碱异构体的电喷雾多级串联质谱分析

采用电喷雾多级串联质谱方法, 通过分子量和多级串联质谱的信息对马钱子总生物碱提取物中微量生物碱异构体伪士的宁、士的宁氮氧化物进行了分析研究; 并研究了异构体质谱碎裂规律与结构之间的关系. 建立了马钱子中生物碱同分异构体区分的简便、快速、灵敏的新方法.